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Yes - of course. Canada has many different immigration programs. Generally speaking, to qualify, you want to have a number of years of paid full time skilled work experience and also have completed higher education. You will also need to show that you have enough funds to resettle yourself in Canada.

You can find detailed information here: http://www.cic.gc.ca/english/immigrate/index.asp
if this is the case, are we suppose to come through Visit visa ?
 
if this is the case, are we suppose to come through Visit visa ?

No - you would apply from your home country and only come to Canada once you are approved as a PR.