1. If you can show proof that you have $10,168 CDN, then by all means apply for the Federal Skilled Worker/Professional Program (FSW); otherwise, you can choose the PNP route.
2. With regard to the PNP, all of the provinces have a requirement that an employer within the province should be willing to employ you based on HRSDC's Labour Market Information. You will find information about all of this from the links provided below.