Others can comment but the moment you put that in your CV I would expect most employers to file your CV in the trash given generally Canadian employers are only interested in someone who has residency status already. As you can imagine there are thousands of people who try the same thing and employers would rather not waste their time on applications where someone may get PR when they have multiple candidates already resident.
In fact unless you have a skill not readily available in Canada it will be very unusual for any employer to respond to any application from anyone outside the country. No harm in trying as you may be lucky.