You should probably do a little more research before asking here.
For starters, look into Quebec's Provincial Nominee Program, see what their requirements are and if you qualify for it.
Then look into CEC (and skilled worker stream) and check out the respective requirements.
Provincial Nominee Programs are a little quicker than any Federal Gov. Immigration Stream but you have to show intent/settle to stay in Quebec. If you lie about this on your application, you application will be invalid, which may or may not mean that your PR might be revoked (which I have never seen, but heard).