A recommendation from your employer won't help at all.
Generally speaking, you need at least one year of skilled work experience either inside or outside of Canada to apply.
You'll need to determine which program you would be applying under and if you meet the requirements and/or have enough points to be selected.
For FSW/Express Entry, you need at least 1 year of continuous work experience in a skilled NOC and would also need to have 480+ points to have a good chance of being selected.
For PNP, the answer will depend on what province you are in. You will need to research the PNP programs for your province.