Just fill a EE profile out and see, but as far I know there's not chance with EE for it (CEC, FSW, FST)
http://www.cic.gc.ca/english/immigrate/skilled/apply-who-express.asp
However you could apply for PGWP and hopefully get some experience.
Inmigration Minister said they want to help PG in EE, just wait and see what happens.
In the meantime take extra care to apply properly for PGWP soon after graduate, all fees payed (255+100 I think), documents (letter from University about finishing your studies, transcripts...), letter of explanation...
Better read some post in this forum about common mistakes with PGWP application like passport expiring sooner than maximum PGWP time, wrong fees or documents..
Perhaps some province have a PNP for graduates without experience, I think Alberta had one, don't hesitate to apply soon, but note PNP are usually slow.