Hi,
the very first thing you need to know is to to see if you qualify for FSW program under three criteria.
1. if you have at least one year of continuous full time or equivalent paid work experience in the last ten years in one or more of the occupational categories identified in the Ministerial Instructions.
Note: The list of occupations can be found at website at: http://www.cic.gc.ca/english/immigrate/skilled/apply-who-instructions.asp
2. If you have an offer of arranged employment in Canada.
3. you are a temporary foreign worker or an international student residing legally in Canada for at least 12 months immediately before submitting your application.
Then please take self-assessment test to calculate your points. this can be done at http://www.cic.gc.ca/english/immigrate/skilled/assess/index.asp .if you have minimum of 67 points then you could start applying.
A complete (easy-to-understand ) instruction guide in filing FSW application can be found at http://www.cic.gc.ca/english/pdf/kits/guides/EG7.pdf.
please also visit:http://www.cic.gc.ca/english/immigrate/skilled/index.asp
Just follow step by step in this form. Let's wait for seniors suggestions.
good luck! Ice cube