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If she has enough points - she can also apply for PR on her own through Express Entry. (She would want to have at least 430 points to have a decent chance of being selected.) This will take time though and she'll need to complete an English test, have her education officially evaluated, etc. So probably in the 10-12 month range (provided she has enough points).
 
What about an open work permit?

Under which rule? She doesn't qualify based on the information you've provided. They're only given out in very specific circumstances.