There are other routes via FSW, you can read about them at this link
http://www.cic.gc.ca/english/immigrate/skilled/index.asp. There
is also an online eligibility tool to make the process a little easier. If none of these are appropriate there is also things like PNP to consider.
Unfortunately, your skills would probably need to be on the occupations under pressure list for the relevant province. These tend to vary and
I'm not sure what they all are but you should be able to find them online somewhere.
Hope you can find something that works for you.