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If you're an existing employee then it's not possible to get it. If you're a past employee then apply for it on the alumni portal.
 
What are the alternative documents which cic will agree?

- Reference letter in CIC format signed by a colleague (include colleagues visiting card)
- payslips
- appointment letter
- appraisal letter (if any)
- tax papers

You will have to provide all these documents.
 
- Reference letter in CIC format signed by a colleague (include colleagues visiting card)
- payslips
- appointment letter
- appraisal letter (if any)
- tax papers

You will have to provide all these documents.
just to add if visiting card not there, colleague official email ID and employee code also suffice the purpose