Working holiday

I am 24 yrs and have recently done MBA. Would like to see Canada while availing Working holiday from Austria. Further planning that on expiry of my Working Holiday visit, would be joining post-secondary Institution at Victoria, BC, Canada. Hope that after six months of my studies in Canada, I would be able to get another work permit as per cic rules. So while living and studying and working in Canada I would be gaining experience of B category of NOC matrix. Then on completion of my Post secondary education I suppose or may get another chance to work for another two years. This is how I will try to become PR by applying at Buffalo. Will this plan work or not. Could you please suggest me better way: thanks