If you or one of your siblings has sufficient income, you can apply to sponsor your parents for a new PR but it will take a while. You can read about it at
http://www.cic.gc.ca/english/immigrate/sponsor/index.aspYou can try H&C grounds but I doubt it will be accepted. Your sister who is 27 years old is a grown woman. Her need of her mothers support will probably not make Canada immigration shed any tears.