There are 3 ways to qualify to apply as a skilled worker under the new rules:
Category 1, you have at least 1 year experience in the last 10 years in one of these occupations:
http://www.cic.gc.ca/english/immigrate/skilled/apply-who-instructions.asp#listCategory 2, you have a job offer (AEO)
Category 3, you are already in Canada as a worker or a student and have been in Canada for the last 12 months or more.
If none of this applies to you, you do not qualify and at some point they will return your application and fees. You can withdraw your application if you wish to and if you fit one of the job codes for Category 1, apply again under that code.