I found this on another post.
1. There are 3 basic methods as a skilled worker. FSW 1 but your occupation has to be on the list of "38" to qualify
http://www.cic.gc.ca/english/department/media/backgrounders/2008/2008-11-28a.asp It would appear that with your present occupation you wouldn't qualify.
2. There are FSW 2/3 which requires that you either are working in Canada as skilled worker or you have an employer who in Canada who is will to employ you permanently in a skilled position once you have received your permanent residence. They have to obtain an Arranged Employment Option from Service Canada
http://www.cic.gc.ca/english/immigrate/skilled/index.asp3. If you wanted to work in Canada for a year as a temporary worker, there is the Bunac visa, which allows you to have an open work permit for a year (only for UK citizens) where you can work at any job.
http://www.bunac.org/UK/workcanada/ You should note that these applications opened in mid december and may all be gone until next december.