not if it gets rejected. Otherwise you can always say you have changed your decision since you have come to know more about Canada- how Alberta economy is doing well and the quality of life,etc.... do prepare a story that sound convincing and has some personal touch in case it is required.
you can also say about a friend who moved to alberta and how they like it if you have one.....
Thanks Leaon, devagirl, ss123
Actually one more question since I already applied on FSW which probably will return back as my NOC code is not in that 38 NOC codes, and in that application I wrote place I'll be staying as Ontario, Can that cause problem applying for Alberta PNP?