You are a Canadian citizen? If yes, your wifes permanent residency is protected because she's married to and staying with a citizen. To return to Canada, she only needs to apply for a PR travel document, see
http://www.cic.gc.ca/english/information/applications/travel.aspShe will fill out her absences from Canada for the last 5 years and include the information that she's has been staying with a Canadian citizen spouse. Once she gets to Canada, she can apply for a PR card, see
http://www.cic.gc.ca/english/information/pr-card/apply-how.aspAs for the kids, as long as they are your kids and you are Canadian, they are Canadian too. You need to apply for their proof of citizenship, see
http://www.cic.gc.ca/english/citizenship/proof.asp You can also apply for their temporary Canadian passports. They can get proper passports when they have their citizenship cards.
You need to talk to the Canadian embassy about all this, see
http://www.dfait-maeci.gc.ca/missions/unitedkingdom-royaumeuni/menu-eng.asp