Processing a student authorization and permanent resident application is not necessarily barred. To state, however, that you have the intention to be a full time student at the time that you would be expected to land as a permanent resident, however, would be contrary to the definition of a skilled worker application.

Unless it can be clearly demonstrated that the period of study would not coincide with your prospective landing, this may result in refusal of one or both of the applications.
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Campbell,Cohen - attorneys at law
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